More than 130 companies are involved in producing or trading the equipment, typically marketed to law enforcement agencies, up from about 28 companies a decade ago, Amnesty said in a report released on Tuesday.
The equipment encourages human rights abuses by law enforcement authorities in African and Southeast Asian nations, the group said.
"While some of the exports are no doubt used in legitimate law enforcement operations, China has also exported equipment that has inhumane effects, or poses a substantial risk of fuelling human rights violations by foreign law enforcement agencies," it said.
One company, China Xining Import/Export Corporation, which advertises thumb cuffs, restraint chairs and electric stun guns, said in 2012 it had ties to more than 40 African countries, according to Amnesty. The firm could not be reached for comment.
'Amnesty biased against China'
The rights group worked with the Britain-based Omega Research Foundation, which researches the trade and the use of military, security and police equipment. Asked about the report, a spokeswoman for China's Ministry of Foreign Affairs said Amnesty was not a reliable group.
"This international organisation is always biased against China and I really doubt the authenticity of the report that has been released," the spokeswoman, Hua Chunying, said on Tuesday.
China is a major investor in resource-rich Africa and the government said in July more than half its foreign aid of more than $14b between 2010 and 2012 was directed to Africa. Torture by law enforcement authorities is a pervasive problem within China. The country's top court said in November it would eliminate the use of torture to extract confessions. Amnesty said news photographs from Ghana, Senegal, Egypt and Madagascar appear to show police toting Chinese made electric shock stun batons.
"Amnesty International and Omega consider that some of the weapons and equipment manufactured in China have inherently abusive effects that are contrary to international human rights standards for law enforcement," the group said.